geckos eat their skin for a good source of vitamins. im not sure if frog molts have the same benefit, but i assume they would (tons of marine inverts use their skin for protien and iodine). ive seen my geckos (and anoles) molt many times. usually it comes off in sections, but it really depends on relative humidity. aslo, the sections easily accesible by the mouht are usually the first to come off, for obvious reasons....
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